硫化物檢測(cè)填充色譜柱
硫化物檢測(cè)填充色譜柱 詳細(xì)信息:
浩瀚色譜(山東)應(yīng)用技術(shù)開發(fā)有限公司建立了利用二維氣相色譜中心切割技術(shù)與雙檢測(cè)器相結(jié)合,測(cè)定硫磺回收加氫過程氣微量硫化物的分析方法。目標(biāo)化合物經(jīng)預(yù)柱分離進(jìn)入熱導(dǎo)檢測(cè)器,同時(shí)通過輔助電子氣路控制系統(tǒng)壓力變化設(shè)定閥切換時(shí)間,將目標(biāo)化合物切入脈沖火焰光度檢測(cè)器進(jìn)行檢測(cè)。確定了加氫過程氣中H2S、SO2、COS、CH3SH、C2H5SH、CS2在柱切換與不切換時(shí)的保留時(shí)間,建立了雙柱、雙檢測(cè)器定性和定量分析方法。該方法進(jìn)行加氫過程氣的分析,目標(biāo)化合物相對(duì)標(biāo)準(zhǔn)偏差RSD<1.0%,低檢出限<1×10-6(體積分?jǐn)?shù)),線性相關(guān)系數(shù)R≥0.999 9。該方法將常量硫化氫與微量硫化物分離,節(jié)省了H2S預(yù)處理步驟,解決了H2S與微量SO2、微量有機(jī)硫共存下硫形態(tài)的準(zhǔn)確定量分析問題
名稱:硫化物測(cè)定專用柱
型號(hào):HH一sulfide-V
規(guī)格:0.475m*3mm
高使用溫度:230°C
編號(hào):
硫化物檢測(cè)填充色譜柱 測(cè)試譜圖:
Sulfide detection packed chromatographic column
Detailed information of sulfide detection packed chromatographic column:
Haohan Chromatography (Shandong) Application Technology Development Co., Ltd. has established an analytical method for the determination of trace sulfides in sulfur recovery and hydrogenation process gas by combining two-dimensional gas chromatography center cutting technology with dual detectors. The target compound is separated by a pre column and enters the thermal conductivity detector. At the same time, the target compound is cut into the pulse flame photometric detector for detection through the auxiliary electronic gas path control system pressure change setting valve switching time. The retention time of H2S, SO2, COS, CH3SH, C2H5SH, and CS2 in the hydrogenation process gas was determined with and without column switching, and a dual column and dual detector qualitative and quantitative analysis method was established. This method is used for the analysis of hydrogenation process gas, and the relative standard deviation (RSD) of the target compound is<1.0%, with a minimum detection limit of<1 × 10-6 (volume fraction), linear correlation coefficient R ≥ 0.999 9. This method completely separates constant hydrogen sulfide from trace sulfide, saving H2S pre-treatment steps and solving the problem of accurate quantitative analysis of sulfur forms under the coexistence of H2S, trace SO2, and trace organic sulfur
Name: Special Column for Sulfide Determination
Model: HH - sulfide V
Specification: 0.475m * 3mm
Maximum operating temperature: 230 ° C
No.:
Sulfide detection packed chromatographic column test spectrum: